Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one

Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one

3-Acyl-5-nitroisoxazoles were synthesized by heating 5,5,5-trinitropentan-2-one with LiCl in DMF at 100 °C as well as by heating oximino derivatives of 5,5,5-trinitro-, 5-chloro-5,5-dinitropentan-2-one or 4,4,4-trinitro- and 4-chloro-4,4-dinitro-1-phenylbutan-1-one in organic solvents.

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Veröffentlicht in:Russian chemical bulletin 2009-10, Vol.58 (10), p.2178-2181
Hauptverfasser: Khisamutdinov, G. Kh, Lyapin, N. M., Nikitin, V. G., Slovetskii, V. I., Fainzil’berg, A. A.
Format: Artikel
Sprache:eng
Schlagworte:
Brief Communications
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:3-Acyl-5-nitroisoxazoles were synthesized by heating 5,5,5-trinitropentan-2-one with LiCl in DMF at 100 °C as well as by heating oximino derivatives of 5,5,5-trinitro-, 5-chloro-5,5-dinitropentan-2-one or 4,4,4-trinitro- and 4-chloro-4,4-dinitro-1-phenylbutan-1-one in organic solvents.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-009-0299-5