New (S)-proline derivatives as catalysts for the enantioselective aldol reaction

New (S)-proline derivatives as catalysts for the enantioselective aldol reaction

(2S)-N- 2-[(R)-Hydroxy(phenyl)methyl]phenyl pyrrolidine-2-carboxamide, (2 S) - N -{2-[( S )-hydroxy(phenyl)methyl]phenyl}pyrrolidine-2-carboxamide, and ( S )- N -{2-[hydroxy-(diphenyl)methyl]phenyl}pyrrolidine-2-carboxamide were obtained and tested as catalysts for an asymmetric aldol reaction of 4-...

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Veröffentlicht in:Russian chemical bulletin 2009-09, Vol.58 (9), p.1903-1907
Hauptverfasser: Maleev, V. I., Gugkaeva, Z. T., Moskalenko, M. A., Tsaloev, A. T., Lyssenko, K. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:(2S)-N- 2-[(R)-Hydroxy(phenyl)methyl]phenyl pyrrolidine-2-carboxamide, (2 S) - N -{2-[( S )-hydroxy(phenyl)methyl]phenyl}pyrrolidine-2-carboxamide, and ( S )- N -{2-[hydroxy-(diphenyl)methyl]phenyl}pyrrolidine-2-carboxamide were obtained and tested as catalysts for an asymmetric aldol reaction of 4-nitrobenzaldehyde with acetone.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-009-0259-0