Hexakis(benzonitrile)ruthenium(II) bis[tetrafluoroborate(1-)]: a precursor to ruthenium organometallic compounds
The new compound, [Ru(NCC 6 H 5 ) 6 ][BF 4 ] 2 , has been synthesized by reaction of the polymeric species [{RuCl 2 (COD)} x ] (COD = 1,5-cyclooctadiene) with benzonitrile under reflux and characterized by elemental analysis, IR, NMR spectroscopic analyses, and single crystal X-ray diffraction. The...
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| Veröffentlicht in: | Research on chemical intermediates 2015-06, Vol.41 (6), p.3817-3823 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The new compound, [Ru(NCC
6
H
5
)
6
][BF
4
]
2
, has been synthesized by reaction of the polymeric species [{RuCl
2
(COD)}
x
] (COD = 1,5-cyclooctadiene) with benzonitrile under reflux and characterized by elemental analysis, IR, NMR spectroscopic analyses, and single crystal X-ray diffraction. The Ru(II) atom is coordinated by six N atoms from six benzonitrile ligands in distorted octahedral coordination geometry. The compound was crystallized in the monoclinic space group
P
2
1
/
c
with unit-cell dimensions
a
= 10.7536(11) Å,
b
= 18.6582(18) Å,
c
= 20.311(2) Å, β = 91.864(2)°,
V
= 4073.2(7) Å
3
and final R of 0.0429. |
|---|---|
| ISSN: | 0922-6168 1568-5675 |
| DOI: | 10.1007/s11164-013-1491-7 |