A comparative study on characterization and photocatalytic activities of gadolinium–boron codoped and mono-doped TiO2 nanoparticles

Gadolinium–boron codoped and mono-doped TiO 2 nanoparticles were prepared using a sol–gel method, and tested for photocatalytic activity by the UV light after a further calcination process. For comparison, a pure TiO 2 sample was also prepared and tested under the same conditions. The prepared catal...

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Veröffentlicht in:Research on chemical intermediates 2012-03, Vol.38 (3-5), p.807-816
Hauptverfasser: Niu, Xinshu, Lu, Xin, Cui, Tianlu, Zhou, Jianguo
Format: Artikel
Sprache:eng
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Zusammenfassung:Gadolinium–boron codoped and mono-doped TiO 2 nanoparticles were prepared using a sol–gel method, and tested for photocatalytic activity by the UV light after a further calcination process. For comparison, a pure TiO 2 sample was also prepared and tested under the same conditions. The prepared catalysts were characterized by X-ray diffraction, scanning electron microscope, and UV–Vis spectra. The photocatalytic activity of the samples was evaluated through the photo-degradation of three different dyes under UV light. The experiments demonstrated that the gadolinium–boron codoped TiO 2 (Gd–B–TiO 2 ) sample calcined at 500 °C possessed the best photocatalytic activity, and the photodegradation rate of the Reactive Brilliant Red K2G aqueous solution could reach to 95.7% under UV irradiation for 80 min. The results showed that Gd–B–TiO 2 has smaller crystallite size and higher photocatalytic activity than that of mono-doped TiO 2 samples and undoped TiO 2 .
ISSN:0922-6168
1568-5675
DOI:10.1007/s11164-011-0419-3