Synthesis, characterization and nonlinear optical properties of new azo compound using CW laser beam

An azo compound, T-3OCH 3 , is synthesized and diagnostics using 1 H and 13 C NMR and mass spectroscopies. The compound theoretical structure is optimized via the DFT/WB97XD approach with a 6-31+G(d,p) basis set level. The compound nonlinear optical properties are studied under irradiation with a vi...

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Veröffentlicht in:Optical and quantum electronics 2024-05, Vol.56 (6), Article 1056
Hauptverfasser: Hussein, Kawkab Ali, Sultan, H. A., Aljaber, Afrah Abdul-Radha’e Mahdi, Hassan, Qusay M. A., Emshary, C. A.
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Sprache:eng
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Zusammenfassung:An azo compound, T-3OCH 3 , is synthesized and diagnostics using 1 H and 13 C NMR and mass spectroscopies. The compound theoretical structure is optimized via the DFT/WB97XD approach with a 6-31+G(d,p) basis set level. The compound nonlinear optical properties are studied under irradiation with a visible CW laser beam via diffraction patterns and the Z-scan. As high as 6.739 × 10 −11  m 2 /W of the nonlinear refraction index is obtained. Static and dynamic all-optical switching are tested in the synthesized compound using two visible CW laser beams.
ISSN:1572-817X
1572-817X
DOI:10.1007/s11082-024-06985-5