Classification of Structural Motifs in Porphyrinic Coordination Polymers Assembled from Porphyrin Building Units, 5,10,15,20-Tetrapyridylporphyrin and Its Derivatives

In this review, we classify 1D, 2D, and 3D structural motifs found in porphyrinic coordination polymers assembled from 5,10,15,20-tetrapyridylporphyrin (TPyP) and its derivatives. The classifications are based on dimensionality, metal-to-porphyrin linkage, porphyrin type, and metal-to-porphyrin ratio. 1D porphyrin polymers often share the same connectivity (or structural motifs) with analogous 2D and 3D polymers. We identify interrelationships among 1D, 2D, and 3D coordination polymers and examine the connectivity of such interrelated structures. We also discuss the broad similarities and differences of the synthetic methods of all structures presented here. Graphical Abstract We classify 1D, 2D, and 3D structural motifs found in porphyrinic coordination polymers assembled from 5,10,15,20-tetrapyridylporphyrin (TPyP) and its derivatives. The classifications are based on dimensionality, metal-to-porphyrin linkage, porphyrin type, and metal-to-porphyrin ratio. We identify interrelationships among 1D, 2D, and 3D coordination polymers and examine the connectivity of such interrelated structures.