Galvanostatic phase formation

The results of a theoretical study on initial stages of electrodeposition under galvanostatic conditions are presented. The model of three-dimensional nucleation and growth under these conditions is developed. This model is used to calculate the times dependences of the overpotential, number of clus...

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Veröffentlicht in:	Journal of solid state electrochemistry 2014, Vol.18 (9), p.2383-2386
Hauptverfasser:	Isaev, Vladimir A., Grishenkova, Olga V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Energy Storage Original Paper Physical Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The results of a theoretical study on initial stages of electrodeposition under galvanostatic conditions are presented. The model of three-dimensional nucleation and growth under these conditions is developed. This model is used to calculate the times dependences of the overpotential, number of clusters formed on the electrode, and nucleation rate. The peculiarities of nucleation and growth kinetics are analyzed.
ISSN:	1432-8488 1433-0768
DOI:	10.1007/s10008-014-2489-9