Preparation and characterization of AuPt alloy nanoparticle–multi-walled carbon nanotube–ionic liquid composite film for electrocatalytic oxidation of cysteine

Gold–platinum (AuPt) alloy particles were fabricated directly on multi-walled carbon nanotubes (MWNT)–ionic liquid (i.e., trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide, [P 6,6,6,14 ][NTf 2 ]) composite coated glassy carbon electrode (GCE) by electrodeposition method. Scanning electron microscope image showed that they were well-dispersed nanocluster consisting of smaller nanoparticles, and their size was about 70 nm. X-ray diffraction experiment showed that they were single-phase alloy nanomaterial, and the calculated composition was consisting with that obtained by energy dispersive X-ray spectroscopy. The resulting modified electrode (i.e., AuPt–MWNT–[P 6,6,6,14 ][NTf 2 ]/GCE) presented high catalytic activity for the electrochemical oxidation of cysteine. The peak potential of cysteine shifted to 0.42 V (versus saturated calomel electrode) in 0.1 M H 2 SO 4 and the peak current increased greatly in comparison with that on the corresponding Pt (or Au)–MWNT–[P 6,6,6,14 ][NTf 2 ]/GCE. Under the optimized conditions, the oxidation current of cysteine at 0.45 V was linear to its concentration in the range of 5.0 × 10 −7 ∼ 4.0 × 10 −5 M with a sensitivity of 43.8 mA M −1 .