Synthesis and characterization of LiClO4·H2O

Synthesis and characterization of LiClO4·H2O

Lithium perchlorate monohydrate was synthesized and characterized. The compound crystallizes isotypic to sodium perchlorate monohydrate in the monoclinic space group type C 2/ c with a  = 14.2592(6) Å, b  = 5.2921(2) Å, c  = 10.3382(4) Å, β  = 111.765(2)°, V  = 724.52(5) Å 3 , Z  = 8, at T  = 110 K....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Monatshefte für Chemie 2016-02, Vol.147 (2), p.279-288
Hauptverfasser: Ivlev, S. I., Akimov, D. V., Egorov, N. B., Kraus, F.
Format: Artikel
Sprache:eng
Schlagworte:
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Original Paper
Physical Chemistry
Theoretical and Computational Chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Lithium perchlorate monohydrate was synthesized and characterized. The compound crystallizes isotypic to sodium perchlorate monohydrate in the monoclinic space group type C 2/ c with a  = 14.2592(6) Å, b  = 5.2921(2) Å, c  = 10.3382(4) Å, β  = 111.765(2)°, V  = 724.52(5) Å 3 , Z  = 8, at T  = 110 K. Additionally, we investigated the compound by means of IR and Raman spectroscopy, powder X-ray diffraction, thermal analysis (TG/DSC), and solid-state computational calculations. Graphical Abstract
ISSN:0026-9247
1434-4475
DOI:10.1007/s00706-015-1603-8