One-pot synthesis of novel s-triazine-containing polyphenols and imidazotriazinium salts

One-pot synthesis of novel s-triazine-containing polyphenols and imidazotriazinium salts

Study of the reaction of aminoacetal containing 1,3,5-triazine moiety with phenols is reported. Reaction conditions leading to the formation of either polyphenols modified with 1,3,5-triazine moiety or previously unknown 6-arylimidazo[1,2- a ][1,3,5]triazin-5-ium salts with good yields are determine...

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Veröffentlicht in:Monatshefte für Chemie 2013-07, Vol.144 (7), p.1027-1030
Hauptverfasser: Gazizov, Almir S., Kharitonova, Natalya I., Burilov, Alexander R., Pudovik, Michail A., Sinyashin, Oleg G.
Format: Artikel
Sprache:eng
Schlagworte:
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Original Paper
Physical Chemistry
Theoretical and Computational Chemistry
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Zusammenfassung:Study of the reaction of aminoacetal containing 1,3,5-triazine moiety with phenols is reported. Reaction conditions leading to the formation of either polyphenols modified with 1,3,5-triazine moiety or previously unknown 6-arylimidazo[1,2- a ][1,3,5]triazin-5-ium salts with good yields are determined. Formation of triazinium salts proceeds via the dearylation of initially formed triazine-containing polyphenols. Graphical abstract .
ISSN:0026-9247
1434-4475
DOI:10.1007/s00706-013-0939-1