ZnO–TiO2 nanocomposites formed under submerged DC arc discharge: preparation, characterization and photocatalytic properties

A rutile TiO 2 (α-TiO 2 ) and hexagonal wurtzite ZnO nanocomposite was directly and synchronously synthesized via arc discharge method submerged in de-ionized water. In correlation with the detailed characterization of the morphology, and crystalline structure of the prepared ZnO–TiO 2 nanocomposite...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2014-09, Vol.116 (3), p.1119-1125
Hauptverfasser: Avcı, Ahmet, Eskizeybek, Volkan, Gülce, Handan, Haspulat, Bircan, Şahin, Ömer Sinan
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Sprache:eng
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Zusammenfassung:A rutile TiO 2 (α-TiO 2 ) and hexagonal wurtzite ZnO nanocomposite was directly and synchronously synthesized via arc discharge method submerged in de-ionized water. In correlation with the detailed characterization of the morphology, and crystalline structure of the prepared ZnO–TiO 2 nanocomposites, the UV–visible and photoluminescence properties were studied. X-ray diffraction and transmission electron microscopy investigations revealed the co-existence of α-TiO 2 and hexagonal wurtzite ZnO phases with the ZnO and α-TiO 2 nanoparticles are in nanorod and nanospheres morphologies, respectively. The diameters of the synthesized nanocomposite particles are in the range of 5–70 nm. Interestingly, the as-prepared ZnO–TiO 2 nanocomposite shows better photocatalytic activity for photodegradation of the methylene blue dye than both of pure ZnO and TiO 2 nanocatalyts. This work would explore feasible routes to synthesize efficient metal or/and metal oxide nanocomposites for degrading organic pollutants, gas sensing or other related applications.
ISSN:0947-8396
1432-0630
DOI:10.1007/s00339-013-8194-1