Synthesis of methyl sterculate

Methyl sterculate was isolated from an irradiation mixture obtained by photolysis of diazomethane in presence of methyl stearolate by column chromatography on silicic acid. The separable amount of the photoproduct was 9.5%. The presence of the cyclopropene structure was proved by spectroscopy and ch...

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Veröffentlicht in:Journal of the American Oil Chemists' Society 1970-03, Vol.47 (3), p.77-78
Hauptverfasser: Altenburger, Erich R., Berry, James W., Deutschman, Archie J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Methyl sterculate was isolated from an irradiation mixture obtained by photolysis of diazomethane in presence of methyl stearolate by column chromatography on silicic acid. The separable amount of the photoproduct was 9.5%. The presence of the cyclopropene structure was proved by spectroscopy and chemical methods.
ISSN:0003-021X
1558-9331
DOI:10.1007/BF02612940