Hydroxymethylation of jojoba oil by Lewis acid-catalyzed ene reaction with formaldehyde

Formaldehyde undergoes ethylaluminum dichloride‐catalyzed ene reaction with jojoba oil to afford a mixture of 1∶1 and 1∶2 adducts. The hydroxymethyl products were identified by comparison with model adducts prepared from methyl oleate and oleyl acetate.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Oil Chemists' Society 1994-02, Vol.71 (2), p.231-232
Hauptverfasser:	McLellan, J.F, Mortier, R.M, Orszulik, S.T, Paton, R.M
Format:	Artikel
Sprache:	eng
Schlagworte:	ACEITES VEGETALES Applied sciences Chemical industry and chemicals CHEMICAL REACTIONS Ene addition Exact sciences and technology FORMALDEHIDOS FORMALDEHYDE HUILE VEGETALE hydroxymethylation JOJOBA jojoba oil Manufacturing and processing methyl oleate Oils and fats oleyl acetate PLANT OILS REACCIONES QUIMICAS REACTION CHIMIQUE SYNTHESIS
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Beschreibung
Zusammenfassung:	Formaldehyde undergoes ethylaluminum dichloride‐catalyzed ene reaction with jojoba oil to afford a mixture of 1∶1 and 1∶2 adducts. The hydroxymethyl products were identified by comparison with model adducts prepared from methyl oleate and oleyl acetate.
ISSN:	0003-021X 1558-9331
DOI:	10.1007/BF02541563