Photoelectronic spectroscopy and mass spectroscopy of the negative ions in molecules of cyclopropyl-substituted butadienes

The photoelectronic spectra of the molecules of some cyclopropylsubstituted butadienes were obtained and interpreted. The processes of the formation of negative ions in dissociative capture of electrons by the molecules of these compounds were studied. The effect of the cyclopropyl groups is primari...

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Veröffentlicht in:	Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Div. Chem. Sci. (Engl. Transl.); (United States), 1985-01, Vol.34 (1), p.69-73
Hauptverfasser:	Furlei, I. I., Sultanov, A. Sh, Khusnutdinov, R. I., Dokichev, V. A., Tolstikov, G. A., Dzhemilev, U. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena ALKYL RADICALS ATOMIC AND MOLECULAR PHYSICS BUTADIENE CAPTURE CHARGED PARTICLES COLLISIONS CONFORMATIONAL CHANGES DIENES DISSOCIATION ELECTRON CAPTURE ELECTRON COLLISIONS ELECTRON SPECTROSCOPY ELECTRON-MOLECULE COLLISIONS ELECTRONIC STRUCTURE ENERGY LEVELS ENERGY RANGE EV RANGE EV RANGE 01-10 HYDROCARBONS INNER-SHELL IONIZATION IONIZATION IONIZATION POTENTIAL IONS MASS SPECTROSCOPY MOLECULAR IONS MOLECULE COLLISIONS ORGANIC COMPOUNDS PHOTOELECTRON SPECTROSCOPY POLYENES PROPYL RADICALS RADICALS SPECTROSCOPY
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Zusammenfassung:	The photoelectronic spectra of the molecules of some cyclopropylsubstituted butadienes were obtained and interpreted. The processes of the formation of negative ions in dissociative capture of electrons by the molecules of these compounds were studied. The effect of the cyclopropyl groups is primarily manifested by destabilization of the molecular negative ion with respect to self-splitting of the electron.
ISSN:	0568-5230 1573-9171
DOI:	10.1007/BF01157330