Influence of electronic structure of diamines on ability to form complexes
To study, the influence of substituents in tetraalkylmethylenediamines on their electron-donor capacity, they studied complexes of molecular iodine with molecules of tetramethyl-methylenediamine (TMMDA) and tetraethylmethylenediamine (TEMDA) in an n-heptane medium at 22/sup 0/C according to electron...
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Veröffentlicht in: | J. Struct. Chem. (Engl. Transl.); (United States) 1985-11, Vol.26 (6), p.946-948 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | To study, the influence of substituents in tetraalkylmethylenediamines on their electron-donor capacity, they studied complexes of molecular iodine with molecules of tetramethyl-methylenediamine (TMMDA) and tetraethylmethylenediamine (TEMDA) in an n-heptane medium at 22/sup 0/C according to electronic absorption spectra. The experiments show that an addition of TMMDA and TEMDA to an iodine solution in n-heptane leads to the formation of charge transfer complexes. |
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ISSN: | 0022-4766 1573-8779 |
DOI: | 10.1007/BF00748369 |