Reaction of phosphorus with iron, cobalt, nickel, and manganese on heating

Reaction of phosphorus with iron, cobalt, nickel, and manganese on heating

X-ray phase, differential thermal, and metallographic analyses are used to study the reaction of phosphorus with Fe, Co, Ni, and Mn on heating in an inert atmosphere. It is found that low-temperature endo- and exothermic effects are related to formation of Fe{sub 3}P, Co{sub 2}P, Ni{sub 3}P, and Mn{...

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Veröffentlicht in:Powder Metallurgy and Metal Ceramics 1994-11, Vol.32 (11-12), p.921-923
Hauptverfasser: Shurin, A. K., Razumova, N. A.
Format: Artikel
Sprache:eng
Schlagworte:
COBALT
COBALT PHOSPHIDES
EUTECTICS
HEATING
IRON
IRON PHOSPHIDES
MANGANESE
MANGANESE PHOSPHIDES
MATERIALS SCIENCE
MELTING
MICROSTRUCTURE
NICKEL
NICKEL PHOSPHIDES
PHOSPHORUS
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Beschreibung
Zusammenfassung:X-ray phase, differential thermal, and metallographic analyses are used to study the reaction of phosphorus with Fe, Co, Ni, and Mn on heating in an inert atmosphere. It is found that low-temperature endo- and exothermic effects are related to formation of Fe{sub 3}P, Co{sub 2}P, Ni{sub 3}P, and Mn{sub 3}P. The effect of eutectic contact melting on the metal-phosphide interface is observed in all specimens.
ISSN:1068-1302
1573-9066
DOI:10.1007/BF00559650