Magnetic isotope effect

Magnetic isotope effect

The electron spin selectivity of radical reactions is accompanied by nuclear spin selectivity, i.e., sorting of the isotopic nuclei relative to their magnetic moment. This property of spin-selective reactions produces separation of magnetic and nonmagnetic isotopes known as the magnetic isotope effe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Theoretical and Experimental Chemistry 1995-11, Vol.31 (3), p.118-126
1. Verfasser: Buchachenko, A. L.
Format: Artikel
Sprache:eng
Schlagworte:
40 CHEMISTRY
ISOTOPE EFFECTS
ISOTOPES
MAGNETIC MOMENTS
MATHEMATICAL MODELS
PHYSICS
RADICALS
SPIN
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The electron spin selectivity of radical reactions is accompanied by nuclear spin selectivity, i.e., sorting of the isotopic nuclei relative to their magnetic moment. This property of spin-selective reactions produces separation of magnetic and nonmagnetic isotopes known as the magnetic isotope effect. The chemical physics of this phenomenon is examined along with the conditions and magnitude of its manifestation as well as the prospects for its use in theoretical and experimental chemistry.
ISSN:0040-5760
1573-935X
DOI:10.1007/BF00538783