Synthesis and properties of charge-transfer complexes based on quaternary salts of amines and tetracyanoquinodimethane

The electrical and optical properties of four charge-transfer complexes based on a molecule of tetracyanoquinodimethane (an acceptor) and donor molecules of quaternary salts of amines have been studied. It has been shown that the conductivity of the complexes has a semiconductor character and is det...

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Veröffentlicht in:	Theor. Exp. Chem. (Engl. Transl.); (United States) 1986-01, Vol.22 (1), p.93-95
Hauptverfasser:	Bondarenko, V. A., Lazar, ., Pokhodnya, K. I., Tanatar, M. A.
Format:	Artikel
Sprache:	eng ; rus
Schlagworte:	360601 - Other Materials- Preparation & Manufacture 360603 - Materials- Properties 400201 - Chemical & Physicochemical Properties ACTIVATION ENERGY ALKANES AMINES AMMONIUM COMPOUNDS AROMATICS BINDING ENERGY CARRIER MOBILITY CHARGE CARRIERS ELECTRIC CONDUCTIVITY ELECTRICAL PROPERTIES ELECTRON TRANSFER ELECTRONS ELEMENTARY PARTICLES ENERGY FERMIONS HYDROCARBONS INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LEPTONS MATERIALS MATERIALS SCIENCE MOBILITY OPTICAL PROPERTIES ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC IODINE COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC OXYGEN COMPOUNDS ORGANIC SEMICONDUCTORS PHYSICAL PROPERTIES QUATERNARY COMPOUNDS QUINONES SEMICONDUCTOR MATERIALS SPECTRA SYNTHESIS TEMPERATURE DEPENDENCE
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Zusammenfassung:	The electrical and optical properties of four charge-transfer complexes based on a molecule of tetracyanoquinodimethane (an acceptor) and donor molecules of quaternary salts of amines have been studied. It has been shown that the conductivity of the complexes has a semiconductor character and is determined by conduction along stacks of tetracyanoquinodimethane molecules.
ISSN:	0040-5760 1573-935X
DOI:	10.1007/BF00525315