The Rovibrational Intensities of the (4001) ← (0000) Pentad Absorption Bands of12C16O2between 7284 and 7921 cm−1

The Rovibrational Intensities of the (4001) ← (0000) Pentad Absorption Bands of12C16O2between 7284 and 7921 cm−1

Absolute line intensities and Herman–Wallis type intensity parameters of12C16O2are experimentally measured for the first time for the (4001)IV← (0000) band at 7460 cm−1and the (4001)I← (0000) band at 7921 cm−1. The rotationless band strengths at 296 K are respectively[formula]and[formula]In addition...

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Veröffentlicht in:Journal of molecular spectroscopy 1996-01, Vol.175 (1), p.104-111
Hauptverfasser: Giver, L.P., Chackerian, Jr, C., Spencer, M.N., Brown, L.R., Wattson, R.B.
Format: Artikel
Sprache:eng
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Zusammenfassung:Absolute line intensities and Herman–Wallis type intensity parameters of12C16O2are experimentally measured for the first time for the (4001)IV← (0000) band at 7460 cm−1and the (4001)I← (0000) band at 7921 cm−1. The rotationless band strengths at 296 K are respectively[formula]and[formula]In addition, previous measurements on the (4001)II← (0000) and (4001)III← (0000) bands have been reanalyzed to be consistent with definitions of Herman–Wallis parameters currently in use.
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1996.0014