Activity coefficients of electrolyte and amino acid in the systems (water + potassium chloride + dl -valine) at T = 298.15 K and (water + sodium chloride + l -valine) at T = 308.15 K

The activity coefficient data were reported for (water + potassium chloride +dl -valine) at T= 298.15 K and (water + sodium chloride +l -valine) at T= 308.15 K. The measurements were performed in an electrochemical cell using ion-selective electrodes. The maximum concentrations of the electrolytes a...

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Veröffentlicht in:The Journal of chemical thermodynamics 2002-08, Vol.34 (8), p.1297-1309
Hauptverfasser: Khavaninzadeh, A., Modarress, H., Taghikhani, V., Khoshkbarchi, M.K.
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Sprache:eng
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Zusammenfassung:The activity coefficient data were reported for (water + potassium chloride +dl -valine) at T= 298.15 K and (water + sodium chloride +l -valine) at T= 308.15 K. The measurements were performed in an electrochemical cell using ion-selective electrodes. The maximum concentrations of the electrolytes and the amino acids studied were 1.0 molality and 0.4 molality, respectively. The results of the activity coefficients of dl -valine are compared with the activity coefficients of dl -valine in (water + sodium chloride +dl -valine) system obtained from the previous study. The results show that the presence of an electrolyte and the nature of its cation have a significant effect on the activity coefficient of dl -valine in aqueous electrolyte solutions.
ISSN:0021-9614
1096-3626
DOI:10.1006/jcht.2002.0959