Activity coefficients of electrolyte and amino acid in the systems (water + potassium chloride + dl -valine) at T = 298.15 K and (water + sodium chloride + l -valine) at T = 308.15 K
The activity coefficient data were reported for (water + potassium chloride +dl -valine) at T= 298.15 K and (water + sodium chloride +l -valine) at T= 308.15 K. The measurements were performed in an electrochemical cell using ion-selective electrodes. The maximum concentrations of the electrolytes a...
Gespeichert in:
Veröffentlicht in: | The Journal of chemical thermodynamics 2002-08, Vol.34 (8), p.1297-1309 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The activity coefficient data were reported for (water + potassium chloride +dl -valine) at T= 298.15 K and (water + sodium chloride +l -valine) at T= 308.15 K. The measurements were performed in an electrochemical cell using ion-selective electrodes. The maximum concentrations of the electrolytes and the amino acids studied were 1.0 molality and 0.4 molality, respectively. The results of the activity coefficients of dl -valine are compared with the activity coefficients of dl -valine in (water + sodium chloride +dl -valine) system obtained from the previous study. The results show that the presence of an electrolyte and the nature of its cation have a significant effect on the activity coefficient of dl -valine in aqueous electrolyte solutions. |
---|---|
ISSN: | 0021-9614 1096-3626 |
DOI: | 10.1006/jcht.2002.0959 |