Micro-combustion calorimetry of coronene
The standard massic energy of combustion of coronene was determined to be −(37.616 ± 0.012)kJ · g−1by means of micro-combustion calorimetry. The standard molar enthalpies of formation of coronene in the crystalline and gaseous phases were found to be (146.5 ± 4.8)kJ · mol−1and (302.0 ± 8.0)kJ · mol−...
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Veröffentlicht in: | The Journal of chemical thermodynamics 2000-08, Vol.32 (8), p.973-977 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The standard massic energy of combustion of coronene was determined to be −(37.616 ± 0.012)kJ · g−1by means of micro-combustion calorimetry. The standard molar enthalpies of formation of coronene in the crystalline and gaseous phases were found to be (146.5 ± 4.8)kJ · mol−1and (302.0 ± 8.0)kJ · mol−1, respectively. The values obtained were very consistent with the literature values. This suggests that the new micro-combustion calorimetric technique is viable for polycyclic aromatic hydrocarbons. |
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ISSN: | 0021-9614 1096-3626 |
DOI: | 10.1006/jcht.2000.0663 |