Influence of Ag on the activity of Zn in {(1−x1−x2)Sn+x1Zn+x2Ag}(l) atT=903 K
The activity of Zn in low-melting {(1−x1−x2)Sn+x1Zn+x2Ag} alloys has been determined by equilibrium saturation with metal vapour atT=903 K. The total content of Zn and Ag was less then 0.3 mole fraction. The interaction parameter ϵZnAgwas determined by the least-squares method. As the method of equi...
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Veröffentlicht in: | The Journal of chemical thermodynamics 1997-09, Vol.29 (9), p.931-939 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The activity of Zn in low-melting {(1−x1−x2)Sn+x1Zn+x2Ag} alloys has been determined by equilibrium saturation with metal vapour atT=903 K. The total content of Zn and Ag was less then 0.3 mole fraction. The interaction parameter ϵZnAgwas determined by the least-squares method. As the method of equilibrium saturation with metal vapour is a comparative one, it is necessary to have an appropriate reference mixture. The {(1−x)Sn+xZn} alloy was assumed to be the appropriate one. |
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ISSN: | 0021-9614 1096-3626 |
DOI: | 10.1006/jcht.1997.0220 |