Densities of (water + carbon dioxide) in the temperature range 415 K to 700 K and pressures up to 35 MPa

New measurements of the amount-of-substance density of 11 mixtures of (water + carbon dioxide) are reported in the temperature range 415 K to 700 K at pressures from 6 MPa to 35 MPa. The results have been obtained using a fully-automated isochoric instrument. The average uncertainty of the density i...

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Veröffentlicht in:The Journal of chemical thermodynamics 1996-04, Vol.28 (4), p.433-446
Hauptverfasser: Fenghour, A., Wakeham, W.A., Watson, J.T.R.
Format: Artikel
Sprache:eng
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Zusammenfassung:New measurements of the amount-of-substance density of 11 mixtures of (water + carbon dioxide) are reported in the temperature range 415 K to 700 K at pressures from 6 MPa to 35 MPa. The results have been obtained using a fully-automated isochoric instrument. The average uncertainty of the density is estimated to be about ± 0.08 per cent for the mixture with the lowest water content, and ± 0.14 per cent for the mixture with the highest water content. Comparisons with independent sources of experimental data through a model based upon the two-fluid corresponding state principle are presented. The dew points of the mixtures studied have also been determined and are compared with values from the Peng-Robinson equation of state.
ISSN:0021-9614
1096-3626
DOI:10.1006/jcht.1996.0043