Enthalpy increments of { xCH 3(CH 2) 3CH 3+ (1 − x)CH 3OH} and of {0.3334CH 3(CH 2) 3CH 3+ 0.3333CH 3OH + 0.3333(CH 3) 2CO} between the temperatures 291 K and 610 K at pressures to 10 MPa
Enthalpy-increment measurements were made on { xCH 3(CH 2) 3CH 3+ (1 − x)CH 3OH} and {0.3334CH 3(CH 2) 3CH 3+ 0.3333CH 3OH + 0.3333(CH 3) 2CO} along isobars from p= 500 kPa to p= 10 MPa, in the temperature range 291 K to 610 K, using a reference-fluid boil-off calorimeter. For { xCH 3(CH 2) 3CH 3+ (...
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Veröffentlicht in: | The Journal of chemical thermodynamics 1995, Vol.27 (3), p.231-243 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Enthalpy-increment measurements were made on {
xCH
3(CH
2)
3CH
3+ (1 −
x)CH
3OH} and {0.3334CH
3(CH
2)
3CH
3+ 0.3333CH
3OH + 0.3333(CH
3)
2CO} along isobars from
p= 500 kPa to
p= 10 MPa, in the temperature range 291 K to 610 K, using a reference-fluid boil-off calorimeter. For {
xCH
3(CH
2)
3CH
3+ (1 −
x)CH
3OH}, measurements were made at
x= 0.25 and
x= 0.75. In addition to the direct calorimetric results, the equation for the enthalpy increments of the liquid and vapor, as well as enthalpy-increment behavior in the supercritical region, are reported. |
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ISSN: | 0021-9614 1096-3626 |
DOI: | 10.1006/jcht.1995.0021 |