Firing Techniques of the Impasti from the Protohistoric Site of Concordia Sagittaria (Venice)

57Fe Mössbauer spectroscopy provided relevant information on the firing techniques employed in manufacturing concotto and coarse pottery, two types of fired clay mixtures (impasti) of the protohistoric settlement site of Concordia Sagittaria. The firing techniques of Concordia were reconstructed by comparing the Mössbauer patterns of the artefacts with those of the local raw clays fired in the laboratory. The concotto was produced in kilns by firing clay mixtures under oxidizing conditions at 700–1000°C, or at lower temperatures in the open air. The firing of these clay mixtures containing mainly ground pieces of waste pottery, resulted in hard and variously coloured construction materials, particularly suitable for humid environments. In turn, the coarse pottery was produced by firing clay mixtures more homogeneous than those used for the artefacts of concotto. The firing of coarse pottery was performed under reducing conditions at about 900°C with a final exposure to air by opening the hot kiln. Light and agreeable coarse pottery, with a red surface on the grey-black core, was obtained when the effective temperature of air was higher than 500°C.