The Crystal Structures of Trimethylphosphane supported Nickel- and Cobalt-Methyl Complexes: Octahedral mer-cis-[CoIIII(CH3)2(PMe3)3] and Square Planar trans-[NiIICl(CH3)(PMe3)2]

The Crystal Structures of Trimethylphosphane supported Nickel- and Cobalt-Methyl Complexes: Octahedral mer-cis-[CoIIII(CH3)2(PMe3)3] and Square Planar trans-[NiIICl(CH3)(PMe3)2]

Single crystals of octahedral mer‐cis‐[CoIIII(CH3)2(PMe3)3] (1) and square planar trans‐[NiIICl(CH3)(PMe3)2] (2), were obtained from solvent mixtures (methylcylohexane / pentane 1:1) and have been analyzed by X‐ray crystallography for the first time.

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2008-09, Vol.634 (11), p.1971-1974
Hauptverfasser: Beck, Robert, Klein, Hans-Friedrich
Format: Artikel
Sprache:eng
Schlagworte:
C ligands
Cobalt
Crystal structure
Nickel
Phosphane
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Zusammenfassung:Single crystals of octahedral mer‐cis‐[CoIIII(CH3)2(PMe3)3] (1) and square planar trans‐[NiIICl(CH3)(PMe3)2] (2), were obtained from solvent mixtures (methylcylohexane / pentane 1:1) and have been analyzed by X‐ray crystallography for the first time.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200800254