Synthesis and Spectroscopic Characterization of a Complex of 1, 10-Phenanthroline with Magnesium

Synthesis and Spectroscopic Characterization of a Complex of 1, 10-Phenanthroline with Magnesium

The complex [Mg(1, 10‐phenanthroline)3(NO3)2]·9H2O has been synthesized. It forms crystals having the shape of sheaves with very thin filaments. The compound has been characterized by UV, IR, NMR and mass spectra. The UV and mass spectra are indicative of an electron density transfer from NO3— to Mg...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2003-01, Vol.629 (1), p.12-14
Hauptverfasser: Dimitrov, Georgi D., Atanassova, Maria S.
Format: Artikel
Sprache:eng
Schlagworte:
1, 10‐Phenanthroline
10-Phenanthroline
Magnesium
Spectroscopic characterization
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Zusammenfassung:The complex [Mg(1, 10‐phenanthroline)3(NO3)2]·9H2O has been synthesized. It forms crystals having the shape of sheaves with very thin filaments. The compound has been characterized by UV, IR, NMR and mass spectra. The UV and mass spectra are indicative of an electron density transfer from NO3— to Mg2+. On the base of the spectroscopic studies a model of the crystal structure has been proposed.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200390005