Fluorine Triggered Surface and Lattice Regulation in Anatase TiO 2- x F x Nanocrystals for Ultrafast Pseudocapacitive Sodium Storage

Sodium-ion batteries (SIBs) have been considered as one of the most promising secondary battery techniques for large-scale energy storage applications. However, developing appropriate electrode materials that can satisfy the demands of long-term cycling and high energy/power capabilities remains a challenge. Herein, a fluorine modulation strategy is reported that can trigger highly active exposed crystal facets in anatase TiO F , while simultaneously inducing improved electron transfer and Na diffusion via lattice regulation. When tested in SIBs, the optimized fluorine doped TiO F nanocrystals exhibit a high reversible capacity of 275 mA h g at 0.05 A g , outstanding rate capability (delivering 129 mA h g at 10 A g ), and remarkable cycling stability with 91% capacity retained after 6000 cycles at 2 A g . Importantly, the optimized TiO F nanocrystals are dominated by pseudocapacitive Na storage, which can be attributed to the fluorine induced surface and lattice regulation, enabling ultrafast electrode kinetics.