Enantiomeric Nanostructures: Chiral Nanostructures from Helical Copolymer-Metal Complexes: Tunable Cation-π Interactions and Sergeants and Soldiers Effect (Small 2/2016)

Enantiomeric Nanostructures: Chiral Nanostructures from Helical Copolymer-Metal Complexes: Tunable Cation-π Interactions and Sergeants and Soldiers Effect (Small 2/2016)

Macroscopically chiral nanospheres and nanotubes composed of helical copolymers are described on page 238 by F. Freire, R. Riguera, and co‐workers. The presence of a donor co‐solvent either activates or deactivates cation–π supramolecular interactions on the chiral monomers of the copolymer, generat...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2016-01, Vol.12 (2), p.237-237
Hauptverfasser: Arias, Sandra, Bergueiro, Julián, Freire, Félix, Quiñoá, Emilio, Riguera, Ricardo
Format: Artikel
Sprache:eng
Schlagworte:
cation-π
enantiomeric nanostructures
helicity
poly(phenylacetylene)s
sergeants and soldiers
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Zusammenfassung:Macroscopically chiral nanospheres and nanotubes composed of helical copolymers are described on page 238 by F. Freire, R. Riguera, and co‐workers. The presence of a donor co‐solvent either activates or deactivates cation–π supramolecular interactions on the chiral monomers of the copolymer, generating either P or M helical senses in the nanostructure through the ‘Sergeants and Soldiers’ effect.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.201670009