Assembly of Artificial Light‐Harvesting Systems Based on Supramolecular Self‐Assembly Metallogels

We have designed and constructed two artificial light‐harvesting systems (ALHSs), which are based on the supramolecular self‐assembly of acylhydrazone functionalized quinoline (L), Al3+ and fluorescent dyes. The L‐Al3+ supramolecular assembly distinctly improved aggregation‐induced emission enhancement and served as a donor for ALHSs. Acridine yellow and acridine orange were found to be good acceptors to realize the energy transfer process with good efficiency. We have constructed two artificial light‐harvesting systems (ALHSs), which are based on acylhydrazone functionalized quinoline (L), Al3+ and fluorescent dyes. The L‐Al3+ supramolecular assembly distinctly improved aggregation‐induced emission enhancement and served as a donor for ALHSs. Acridine yellow and acridine orange were found to be good acceptors to accomplish the energy transfer process with good efficiency.