Ni/Ni 12 P 5 Heterostructure Decorated on Multi‐channel Carbonized Wood Frameworks for Efficient Hydrogen Evolution

For exploiting high‐efficiency and stable non‐noble metal hydrogen evolution reaction (HER) electrocatalysts, rationally design and optimizing the electrode structures are extremely essential. Herein, inspired by the abundant pores and highly ordered multi‐channel structures of natural wood, a typical electrode with Ni/Ni 12 P 5 heterostructure embedded in the multi‐channel carbonized wood frameworks (Ni/Ni 12 P 5 /CW) was designed and fabricated. The open micro‐channel structure and electrical conductivity of carbonized wood (CW) facilitates electron transfer, electrolyte penetration, and gas diffusion. Meanwhile, formation of the Ni/Ni 12 P 5 heterostructure is beneficial to improve the activity of pristine nickel phosphide. As expected, the Ni/Ni 12 P 5 /CW electrode exhibited excellent HER catalytic activity, which merely needed overpotentials of 86, 138 and 173 mV to drive 10, 50 and 100 mA cm −2 in alkaline media, respectively. In addition, it showed superior durability with no significant degradation for more than 60 h of continuous operation at different current densities. This work will enlighten the development and utilization of wood‐based materials for application in electrocatalysis.