Enantioselective Syntheses of Axially Chiral Phosphonates or Phosphine Oxides via Asymmetric Suzuki Reactions with Chiral Sulfinamide Monophosphine Ligands

A class of chiral sulfinamide monophosphine ligands Ming‐Phos were firstly employed in the asymmetric Suzuki coupling reactions. Using the in‐situ formed catalyst from PdCl2 and (R, SS)‐M07, 22 axially chiral phosphonates or phosphine oxides were successfully synthesized in 29−99% yields with up to...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	ChemistrySelect (Weinheim) 2019-05, Vol.4 (17), p.5122-5125
Hauptverfasser:	Zhang, Yaqi, Li, Yongsu, Pan, Bendu, Xu, Hao, Liang, Hao, Jiang, Xiaoding, Liu, Binyun, Tse, Man‐Kin, Qiu, Liqin
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric synthesis Axial chirality biaryl compounds Phosphine Ligands Suzuki reaction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!