Secondary-ion mass spectrometry methodology and surface chemistry of mixed oxide electrodes: Modifications induced by noble-metal content

Mixed‐oxide coatings are extensively used in the electrochemical industry. Secondary‐ion mass spectrometric data confirm that technological research can indeed find a new way of controlling precursors, synthesis conditions, purity of coatings and electrodic activity. Results obtained by argon and oxygen primary‐ion bombardment of RuO2/TiO2, IrO2/TiO2, RuO2/IrO2/TiO2 films are reported. The presence of metal, metal oxide and cluster ions suggests a more systematic use of secondary‐ion mass spectrometry in the elucidation of catalytic aspects. In‐depth profiles of some ionic species and their correlation with parameters that induce significant modifications can help in the understanding of the solid state physics and inorganic chemistry involved.