Novel cationically polymerizable propenyl and vinyl ethers derived from renewable sources

The preparation of several novel mono‐ and dipropenyl and divinyl ethers derived from renewable starting materials is described using simple, straightforward synthetic methods. Utilizing real‐time infrared spectroscopy, the reactivity of the monomers in photoinitiated cationic polymerization was stu...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1994-11, Vol.32 (15), p.2919-2930
Hauptverfasser:	Crivello, J. V., Bratslavsky, S. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences biorenewable monomers cationic photopolymerization Exact sciences and technology Physicochemistry of polymers Polymerization Polymers and radiations propenyl ethers vinyl ethers
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Beschreibung
Zusammenfassung:	The preparation of several novel mono‐ and dipropenyl and divinyl ethers derived from renewable starting materials is described using simple, straightforward synthetic methods. Utilizing real‐time infrared spectroscopy, the reactivity of the monomers in photoinitiated cationic polymerization was studied employing diaryliodonium and triarylsulfonium salts as photoinitiators. The monomers were shown to undergo very rapid cationic photopolymerization. © 1994 John Wiley & Sons, Inc.
ISSN:	0887-624X 1099-0518
DOI:	10.1002/pola.1994.080321513