High solids content emulsion terpolymerization of vinyl acetate, methyl methacrylate and butyl acrylate. II. Open loop composition control

A method for the calculation of the optimal monomer addition policies for polymer composition control in emulsion terpolymerization is developed. The method is applied to reactors with and without limited heat removal capacity. A mathematical model that incorporates the main features of the vinyl ac...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1994-07, Vol.32 (9), p.1779-1788
Hauptverfasser:	Urretabizkaia, Agustín, Arzamendi, Gurutze, Unzué, María J., Asua, José M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences composition control Copolymerization emulsion terpolymerization Exact sciences and technology high solids content Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
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Beschreibung
Zusammenfassung:	A method for the calculation of the optimal monomer addition policies for polymer composition control in emulsion terpolymerization is developed. The method is applied to reactors with and without limited heat removal capacity. A mathematical model that incorporates the main features of the vinyl acetate/methyl methacrylate/butyl acrylate high solids content emulsion terpolymerization system allows the calculation of the composition of the initial charge of the reactor and the time‐dependent monomer addition rates required. © 1994 John Wiley & Sons, Inc.
ISSN:	0887-624X 1099-0518
DOI:	10.1002/pola.1994.080320920