Radiation-grafted ion-exchange membranes: Influence of the initial matrix on the synthesis and structure

A series of commercial fluoropolymer films was irradiated with an electron beam, grafted with styrene, and sulfonated. The influence of the initial fluoropolymer on the grafting yields and the properties of the grafted and sulfonated membranes were investigated. The same synthesis procedure can be followed for most fluoropolymers and samples with a similar degree of grafting, and a homogenous polystyrene distribution can be prepared by varying the absorbed dose. The main difference among different fluoropolymer‐based membranes is the water uptake from liquid water that has a roughly linear dependence on the crystallinity of the sample. The more amorphous the initial material, the greater the water uptake. Mechanical properties of the membranes at 50% relative humidity differ less than those of the starting materials and are comparable to those of Nafion® 105. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3008–3017, 2001 A series of radiation‐grafted membranes based on different fluoropolymers but with similar polystyrene sulfonic acid contents was synthesized and characterized. The specific influence of the initial fluoropolymer was investigated. The membranes have much in common. The main difference concerns the water uptake that varies roughly linearly with the crystallinity.