N ‐vinylthiopyrrolidinone

The polymerization reactivity of N‐vinylthipyrrolidinone is described. This monomer readily homopolymerizes and forms copolymers with a wide variety of vinyl monomers. Reactivity ratios in the copolymerization of N ‐vinylthiopyrrolidinone with styrene and methyl methacrylate are reported and the Alf...

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Veröffentlicht in:Journal of polymer science. Part A-1, Polymer chemistry Polymer chemistry, 1970-08, Vol.8 (8), p.2073-2078
Hauptverfasser: Coleman, L. E., Bork, J. F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The polymerization reactivity of N‐vinylthipyrrolidinone is described. This monomer readily homopolymerizes and forms copolymers with a wide variety of vinyl monomers. Reactivity ratios in the copolymerization of N ‐vinylthiopyrrolidinone with styrene and methyl methacrylate are reported and the Alfrey‐Price Q and e values calculated. These results indicate the high copolymerization reactivity of this monomer in comparison with the oxo‐analog, N ‐vinylpyrrolidinone. Some of the results are in conflict with previously reported data.
ISSN:0449-296X
1542-9350
DOI:10.1002/pol.1970.150080815