Zinc oxide‐sensitized photopolymerization
Zinc oxide under ultraviolet excitation causes the polymerization of vinyl monomers if water and oxygen are present. Analysis shows that hydroxyl radicals initiate the chain. Hydrogen peroxide is produced with light‐excited zinc oxide and is further decomposed by the reducing action of excited zinc...
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| Veröffentlicht in: | Journal of polymer science. Part A-1, Polymer chemistry Polymer chemistry, 1966-07, Vol.4 (7), p.1683-1688 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Zinc oxide under ultraviolet excitation causes the polymerization of vinyl monomers if water and oxygen are present. Analysis shows that hydroxyl radicals initiate the chain. Hydrogen peroxide is produced with light‐excited zinc oxide and is further decomposed by the reducing action of excited zinc oxide. |
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| ISSN: | 0449-296X 1542-9350 |
| DOI: | 10.1002/pol.1966.150040703 |