Kinetics of mutual radiation grafting of styrene in ethyl cellulose film

Kinetics of mutual radiation grafting of styrene in ethyl cellulose film

A general procedure is described by means of which the kp/kt1/2 ratio can be determined for the graft polymerization of vinyl monomers in an organic substrate. The method takes rigorous account of the influence of monomer diffusion on the reaction kinetics. As an experimental example, the mutual rad...

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Veröffentlicht in:J. Polymer Sci 1962-01, Vol.56 (163), p.69-81
Hauptverfasser: Mock, Richard A., Vanderkooi, William N.
Format: Artikel
Sprache:eng
Schlagworte:
CELLULOSE
CHEMISTRY
DIFFUSION
ELECTRONS
ETHYL RADICALS
FREE RADICALS
GRAFT POLYMERS
LAYERS
POLYMERIZATION
POLYMERS
REACTION KINETICS
STYRENE
VAN DE GRAAFF ACCELERATORS
VINYL RADICALS
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Beschreibung
Zusammenfassung:A general procedure is described by means of which the kp/kt1/2 ratio can be determined for the graft polymerization of vinyl monomers in an organic substrate. The method takes rigorous account of the influence of monomer diffusion on the reaction kinetics. As an experimental example, the mutual radiation grafting of styrene onto ethyl cellulose film by use of 2‐M.e.v. Van de Graaff electrons to initiate free radical formation is described in detail.
ISSN:0022-3832
1542-6238
DOI:10.1002/pol.1962.1205616308