Endgroups in tetrafluoroethylene polymers
The aqueous polymerization of tetrafluoroethylene initiated with ammonium persulfate in neutral or relatively weak acid solutions leads to polymer containing carboxyl end groups. The conversion of this endgroup to the sodium salt and its pyrolysis to the terminal olefin was followed, using infrared...
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| Veröffentlicht in: | Journal of polymer science 1959-08, Vol.38 (134), p.289-295 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The aqueous polymerization of tetrafluoroethylene initiated with ammonium persulfate in neutral or relatively weak acid solutions leads to polymer containing carboxyl end groups. The conversion of this endgroup to the sodium salt and its pyrolysis to the terminal olefin was followed, using infrared absorption technique. |
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| ISSN: | 0022-3832 1542-6238 |
| DOI: | 10.1002/pol.1959.1203813401 |