Reactions of 1,3‐dihaloadamantanes with diphenylphosphide ions by the S RN 1 mechanism. Competition between intermolecular and intramolecular electron transfer reactions
The reactivity of 1,3‐dihaloadamantanes with diphenylphosphide ions (Ph 2 P − ) in liquid ammonia was studied. 1,3‐Dichloroadamantane (1a), 1‐bromo‐3‐chloroadamantane (1b) and 1,3‐dibromoadamantane (1c) reacted with Ph 2 P − ions under photostimulation by the S RN 1 mechanism. Irradiation of 1c with...
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| Veröffentlicht in: | Journal of physical organic chemistry 1994-11, Vol.7 (11), p.610-614 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reactivity of 1,3‐dihaloadamantanes with diphenylphosphide ions (Ph
2
P
−
) in liquid ammonia was studied. 1,3‐Dichloroadamantane (1a), 1‐bromo‐3‐chloroadamantane (1b) and 1,3‐dibromoadamantane (1c) reacted with Ph
2
P
−
ions under photostimulation by the S
RN
1 mechanism. Irradiation of 1c without Ph
2
P
−
ions gave no reaction ( |
|---|---|
| ISSN: | 0894-3230 1099-1395 |
| DOI: | 10.1002/poc.610071104 |