Tandem mass spectrometry of aminated fullerene derivatives

Tandem mass spectrometry of aminated fullerene derivatives

The products of the reaction between fullerenes (C60/C70) and dimethylamine were investigated by fast atom bombardment (FAB) mass spectrometry and tandem mass spectrometry (MS/MS). The FAB mass spectrum shows peaks corresponding to the addition of up to eight dimethylamine species, exclusively to C7...

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Veröffentlicht in:Organic Mass Spectrometry 1993-05, Vol.28 (5), p.559-563
Hauptverfasser: Davey, Simon N., Tetler, Lee W., Leigh, David A., Moody, Andrew E.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Mass spectrometry
Organic chemistry
Reactivity and mechanisms
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Zusammenfassung:The products of the reaction between fullerenes (C60/C70) and dimethylamine were investigated by fast atom bombardment (FAB) mass spectrometry and tandem mass spectrometry (MS/MS). The FAB mass spectrum shows peaks corresponding to the addition of up to eight dimethylamine species, exclusively to C70. MS/MS reveals an unusual fragmentation pattern. The mass spectrum of the reaction products, together with a number of tandem mass spectra, are shown.
ISSN:0030-493X
1096-9888
2376-3884
DOI:10.1002/oms.1210280515