A study of deuterium exchange in adamantane carboxylic acids and alcohols under electron impact

A study of deuterium exchange in adamantane carboxylic acids and alcohols under electron impact

The mass spectra of 1‐adamantyl substituted carboxylic acids and alcohols with and without deuterated hydroxyl groups were studied. Deuterium exchange between functional group and adamantane nucleus was observed and a possible explantation of the phenomenon is given.

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Veröffentlicht in:Organic Mass Spectrometry 1977-02, Vol.12 (2), p.98-99
Hauptverfasser: Yurchenko, A. G., Dovgan, N. L., Chizhov, O. S., Karpenko, N. F., Ya. Podel'ko, A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The mass spectra of 1‐adamantyl substituted carboxylic acids and alcohols with and without deuterated hydroxyl groups were studied. Deuterium exchange between functional group and adamantane nucleus was observed and a possible explantation of the phenomenon is given.
ISSN:0030-493X
1096-9888
DOI:10.1002/oms.1210120210