The influence of stereochemistry on the mass spectra of some trimethylsilylated pyranoses
The relative intensities of certain ions in the mass spectra of trimethylsilylated pyranoses have been observed to depend on the stereochemistry of the molecule. A system has been developed which is capable of explaining the differences between the anomeric forms of D‐glucose, D‐galactose, D‐mannose...
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| Veröffentlicht in: | Organic Mass Spectrometry 1971-11, Vol.5 (11), p.1273-1276 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The relative intensities of certain ions in the mass spectra of trimethylsilylated pyranoses have been observed to depend on the stereochemistry of the molecule. A system has been developed which is capable of explaining the differences between the anomeric forms of D‐glucose, D‐galactose, D‐mannose and D‐xylose. |
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| ISSN: | 0030-493X 1096-9888 |
| DOI: | 10.1002/oms.1210051104 |