1 H and 13 C nuclear magnetic resonance study of ( D 3 )‐trishomocuban‐4‐ol and ( D 3 )‐trishomocubanone

1 H and 13 C nuclear magnetic resonance study of ( D 3 )‐trishomocuban‐4‐ol and ( D 3 )‐trishomocubanone

The complete assignments of the 1 H and 13 C NMR spectra for ( D 3 )‐trishomocuban‐4‐ol (3) and ( D 3 )‐trishomocubanone (4) are reported. The difference between the 1 H and 13 C chemical shifts of 3 and 4 and those of the hydrocarbon ( D 3 )‐trishomocubane, and the substituent effect of the hydroxy...

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Veröffentlicht in:Organic magnetic resonance 1981-02, Vol.15 (2), p.188-192
Hauptverfasser: Dekker, Theodor G., Oliver, Douglas W., Pachler, Klaus G. R., Wessels, Philippus L., Woudenberg, Marianne
Format: Artikel
Sprache:eng
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Zusammenfassung:The complete assignments of the 1 H and 13 C NMR spectra for ( D 3 )‐trishomocuban‐4‐ol (3) and ( D 3 )‐trishomocubanone (4) are reported. The difference between the 1 H and 13 C chemical shifts of 3 and 4 and those of the hydrocarbon ( D 3 )‐trishomocubane, and the substituent effect of the hydroxy group, can be adequately explained by the unique stereochemistry of these compounds.
ISSN:0030-4921
DOI:10.1002/mrc.1270150213