Chemically induced polarisation in the decomposition of 2-methyltetrahydrofuran hydroperoxide

Chemically induced polarisation in the decomposition of 2-methyltetrahydrofuran hydroperoxide

The CIDNP effects observed during thermal decomposition of 2‐hydroperoxide‐2‐methyltetrahydrofuran at 150° in C6H5COH are described. An A/E multiplet effect is observed on the CH3‐propyl protons of the propylacetate formed as a result of decyclisation of the methylfuryl radical.

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Veröffentlicht in:Organic Magnetic Resonance 1973-05, Vol.5 (5), p.219-220
Hauptverfasser: Ignatenko, A. V., Kessenikh, A. V., Glukhovtsev, V. G., Nadtochii, M. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The CIDNP effects observed during thermal decomposition of 2‐hydroperoxide‐2‐methyltetrahydrofuran at 150° in C6H5COH are described. An A/E multiplet effect is observed on the CH3‐propyl protons of the propylacetate formed as a result of decyclisation of the methylfuryl radical.
ISSN:0030-4921
1097-458X
DOI:10.1002/mrc.1270050505