Determination and assignment of heteronuclear 119 Sn 1 H coupling constants

n J ( 119 Sn, 1 H) coupling constants were determined by 2D 13 C 1 H and 119 Sn 1 H non‐refocused COLOC (TPPI) correlation methods. As the 2D 13 C 1 H method only gives access to coupling constants directly measured from the spectra, the proposed non‐refocused COLOC technique is more general sinc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry 1993-02, Vol.31 (2), p.176-181
Hauptverfasser: Ratier, Max, Jousseaume, Bernard, Noiret, Nicolas, Petit, Nathalie, Lartigue, Jean‐Claude, Pétraud, Michel
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:n J ( 119 Sn, 1 H) coupling constants were determined by 2D 13 C 1 H and 119 Sn 1 H non‐refocused COLOC (TPPI) correlation methods. As the 2D 13 C 1 H method only gives access to coupling constants directly measured from the spectra, the proposed non‐refocused COLOC technique is more general since it allows measurements in the case of satellites which are non‐observable in 13 C NMR spectra. An optimization method for the τ value in COLOC experiments is also proposed.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.1260310204