Carbon-13 NMR of some organophosphorus compounds. 5-2-oxo- or 2-thio-2-, 3-, 4-, 5-, or 6-substituted 1,3,2-oxazaphosphorinanes and related P(IV) compounds

Carbon-13 NMR of some organophosphorus compounds. 5-2-oxo- or 2-thio-2-, 3-, 4-, 5-, or 6-substituted 1,3,2-oxazaphosphorinanes and related P(IV) compounds

The 13C chemical shifts and PC coupling constants of nine 2‐oxo‐ or 2‐thio‐2‐, 3‐, 4‐, 5‐ or 6‐substituted 1,3,2‐oxazaphosphorinanes, with various groups attached to the ring carbon phosphorus and nitrogen atoms have been analysed. Some aspects of the stereochemistry of these compounds are verified....

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Veröffentlicht in:Magnetic resonance in chemistry 1985-11, Vol.23 (11), p.925-928
Hauptverfasser: Al-Rawi, Jassim M. A., Ayed, Naceur, Kraemer, Raymond, Navech, Jacques
Format: Artikel
Sprache:eng
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Zusammenfassung:The 13C chemical shifts and PC coupling constants of nine 2‐oxo‐ or 2‐thio‐2‐, 3‐, 4‐, 5‐ or 6‐substituted 1,3,2‐oxazaphosphorinanes, with various groups attached to the ring carbon phosphorus and nitrogen atoms have been analysed. Some aspects of the stereochemistry of these compounds are verified.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.1260231109