Nitroxide-Mediated Radical Polymerization in Miniemulsion at Stationary State: Rationale for Independence of Polymerization Rate on Nitroxide Partitioning Using Oil-Phase Initiation

Simulations based on the kinetics and mechanism of nitroxide‐mediated free radical polymerization (NMP) have been carried out in order to understand the hitherto largely unexplained effects (or lack thereof) of nitroxide partitioning in aqueous miniemulsion NMP. The focus has been on the miniemulsio...

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Veröffentlicht in:	Macromolecular theory and simulations 2005-08, Vol.14 (7), p.415-420
Hauptverfasser:	Zetterlund, Per B., Okubo, Masayoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences controlled/living polymerization Exact sciences and technology kinetics (polym.) miniemulsion nitroxides Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts radical polymerization
Online-Zugang:	Volltext
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