Weak segregation in molten statistical copolymers
We present a qualitative argument suggesting that a statistical (AB) copolymer should display a certain form of weak segregation, with A rich and B rich regions of size comparable to the coil radius. This should occur if the Flory parameter χ is larger than unity (much larger than for the phase sepa...
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Veröffentlicht in: | Macromolecular symposia. 2003-03, Vol.191 (1), p.7-10 |
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Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | We present a qualitative argument suggesting that a statistical (AB) copolymer should display a certain form of weak segregation, with A rich and B rich regions of size comparable to the coil radius. This should occur if the Flory parameter χ is larger than unity (much larger than for the phase separation of A and B of homopolymers) in agreement with detailed calculations by Frederikson, Milner and Leibler. We achieve a certain qualitative insight for the resulting microphase. |
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ISSN: | 1022-1360 1521-3900 |
DOI: | 10.1002/masy.200390016 |